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i-manager's Journal on Material Science (JMS)

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Exploring the Optical and Structural Properties of Chromium (Cr)-Doped Polyaniline
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Advancements and Applications of Piezoelectric Energy Harvesters: A Comprehensive Review

Most Cited

Volume 2 Issue 1 April - June 2014

Research Paper

Effect Of Compositional Variation Of The Physical Parameters Of Ge-Se-In Glass System

Surbhi Sharma* , Amit Sarin, Navjeet Sharma*

* Research Scholar, Punjab Technical University, Kapurthala, India

Department of Physics, Amritsar College of Engineering & Technology, Amritsar, India

* Department of Physics, DAV College, Jalandhar, India

Sharma, S., Sarin, A., & Sharma, N. (2014). Effect of Compositional Variation of the Physical Parameters of Ge-Se-In Glass System. i-manager's Journal on Material Science, 2(1), 1-6. https://doi.org/10.26634/jms.2.1.2757

Abstract

In this paper an attempt has been made to theoretically find the variation of some important parameters of one of the arsenic fre Ge-Se glass system by the addition of In content. Various parameters like co-ordination number, floppy modes, bond energy, electro negativity, heat of atomization, cohesive energy and glass transition temperature have been calculated for Ge Se In (x=0,1,2,3,4,5,6) glass system. Glass transition temperature (Tg) is calculated by using 16 84-x x two approaches i.e. Tichy-Ticha and Lankhorst approaches. Tg seems to be increasing in theoretical calculations while average single bond energy is decreasing with the increase in the content of In.

References

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[5]. J.C Phillips, (1979). "Topology of Covalent Non- Crystalline Solids 1: Short Range order in Chalcogenide Alloys", Journal of non-crystalline solids, Vol. 34, pp. 153.

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[7]. R. Zallen, (1983). The Physics of Amorphous Solids, NewYork, Wiley.

[8]. Prashant Kumar, Vivek Modgil, Subhash Chand , V.S. Rangra, "The Study of Physical Parameters of Pb Modified Germanate Chalcogenide Glass", Journal of nano- and electronic, Vol. 5 No 4, 04076(6pp), 2013.

[9]. A. Dahshan and K. A. Aly, (2008). "Characterization of New Quaternary Chalcogenide As-Ge-Se-Sb Thin Films," Philosophical Magazine, Vol. 88, No. 3, pp. 361-372,

[10]. L.Tichy and H.Ticha, (1994). "On the chemical Threshold in Chacogenide Glasses," Materials Letters, Vol. 2, No. 3-4, pp. 313-319.

[11]. L.Tichy and Ticha, (1995). "Covalent Bond Approch to the glass transition temperature of Chalcogenide Glasses", Journal of Non- crystalline Solids, Vol 189, No 1-2, pp 141- 146.

[12]. William D. Callister, (2001). "Fundamentals of Material Sciences and Engineering" Edition 5, John Willey and Sons.

[13]. C.Kittle, (1949). "Interpretation of thermal conductivity of glasses", Physical Review, 75(9), pp. 972-974.

[14]. M.H.R Lankhorst, (2002). "Modelling Glass Transition Temperatures of chalcogenide glasses, Applied to Phase – Change optical Recording", Journal of Non Crystalline Solids, Vol 297 (2-3), pp. 210- 219.

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Research Paper

Mechanical And Metallurgical Characterisation Of Friction Stir Welded Aluminium Alloys AA5083-O And AA6061-T4

Kudzanayi Chiteka* , Narayana Yuvaraj**

*-** Production Engineering, Delhi Technological University, India.

Chiteka, K., & Yuvaraj, N. (2014). Mechanical and Metallurgical Characterisation of Friction Stir Welded Aluminium Alloys Aa5083-O And Aa6061-T4. i-manager's Journal on Material Science, 2(1), 7-14. https://doi.org/10.26634/jms.2.1.2758

Abstract

This research presents the mechanical and metallurgical properties of dissimilar joints of AA5083-O and AA6061-T4 aluminum alloy. Two rotational speeds, 630 and 1600 rpm and three traverse speeds 16, 25, and 40 mm/min were applied to perform the joining process. Macrostructural observations were done to evaluate the weld quality and some semi-circular profiles appeared on the trailing side of the weld and flash were also visible on the retreating side of the joint. Optical microscopy was used to determine the orientation and distribution of the grains in the weld and the adjacent zones. Dynamic recrystallization was evident in the dissimilar joint and the fine grain structure confirmed this. The material in the stir zone contained a mixture of both materials but AA6061-T4 which was fixed on the advancing side dominated the stir zone and thus it influenced the joint performance. Mechanical properties of the joints i.e. ultimate strength, elongation, and microhardness were determined for different weld zones and material combinations. Material combinations included joints made of similar AA5083-O or AA6061-T4 as well as dissimilar joints of AA5083-O and AA6061-T4. The dissimilar joint exhibited intermediate mechanical properties. Hardness values were generally less in the advancing side compared to the retreating side and also they increased from the bottom towards the top of the joint.

References

[1]. R. Palanivel., P. Koshy Mathews, (2012). Prediction and optimization of process parameter of friction stir welded AA5083- H111 aluminum alloy using response surface methodology, J. Cent. South Univ. 19 1?8.

[2]. I. Shigematsu., Y.-J. Kwon., K. Suzuki., T. Imai., N. Saito., (2003). Joining of 5083 and 6061 aluminum alloys by friction stir welding, Journal Of Materials Science, Letters 22, 353– 356.

[3]. Y. K. Yousif., K. M. Daws., B. I. Kazem., (2008). Prediction of Friction Stir Welding Characteristic Using Neural Network, Jordan Journal of Mechanical and Industrial Engineering , Volume 2, Number 3, 151 – 155.

[4]. P.M.G.P. Moreira., T. Santos., S.M.O. Tavares., V. Richter- Trummer., P. Vilaça., P.M.S.T. de Castro., (2009). Mechanical and metallurgical characterization of friction stir welding joints of AA6061-T6 with AA6082-T6, Materials and Design, 30, 180–187.

[5]. M. Ghosh., K. Kumar., S.V. Kailas., A.K. Ray., (2010). Optimization of friction stir welding parameters for dissimilar aluminum alloys, Materials and Design, 31, 3033– 3037.

[6]. T. L. Dickerson, and J. Przydatek, (2003). Fatigue of friction stir welds in aluminum alloys that contain root flaws. Int. J. Fatigue, 25, 1399–1409.

[7]. P. Bahemmat., M. Haghpanahi., M.K. Besharati., S. Ahsanizadeh., H. Rezaei., (2010). Study on mechanical, micro-, and macrostructural characteristics of dissimilar friction stir welding of AA6061-T6 and AA7075-T6, Proceedings of the Institution of Mechanical Engineers, Part B: Journal of Engineering Manufacture, 224: 1854.

[8]. Ákos Meilinger., Imre Török., (2013). The Importance of Friction Stir Welding Tool, Production Processes and Systems, Vol. 6. No. 1., pp. 25-34.

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[10]. Hidetoshi Fujii., Ling Cui., Masakatsu Maeda., Kiyoshi Nogi., (2006). Effect of tool shape on mechanical properties and microstructure of friction stir welded aluminum alloys, Materials Science and Engineering, A 419, 25–31.

[11]. Min-Su Han., Seung-Jun Lee., Jae-Cheul Park., Seok- Cheol KO., Yong-Bin Woo., Seong-Jong Kim., (2009). “Optimum condition by mechanical characteristic evaluation in friction stir welding for 5083-O Al alloy”, Trans. Nonferrous Met. Soc. China 19 s17-s22.

[12]. R. Palanivel, P. Koshy Mathews, N. Murugan, I. Dinaharan, (2012). Effect of tool rotational speed and pin profile on microstructure and tensile strength of dissimilar friction stir welded AA5083-H111 and AA6351-T6 aluminum alloys, Materials and Design, 40, 7–16.

[13]. Damjan Klobcar., Ladislav Kosec., Adam Pietras., Anton Smolej., (2012). Friction-Stir Welding Of Aluminium Alloy 5083, Materials and technology 46 5, 483–488.

[14]. A. Heidarzadeh., H. Khodaverdizadeh., A. Mahmoudi., E. Nazari., (2012). Tensile behaviour of friction stir welded AA 6061-T4 aluminum alloy joints, Materials and Design, 37, 166–173.

[15]. I. Dinaharan., K. Kalaiselvan., S.J. Vijay, P. Raja., (2012). Effect of material location and tool rotational speed on microstructure and tensile strength of dissimilar friction stir welded aluminum alloys, Archives of civil and mechanical engineering, 12, 446 –454.

[16]. Won-Bae Lee., Yun-Mo Yeon., Seung-Boo Jung., (2003). The joint properties of dissimilar formed Al alloys by friction stir welding according to the fixed location of materials, Scripta Materialia, 49, 423–428.

[17]. S.T. Amancio-Filho., S. Sheikhi., J.F. dos Santos., C. Bolfarini., (2008). Preliminary study on the microstructure and mechanical properties of dissimilar friction stir welds in aircraft aluminium alloys 2024-T351 and 6056-T4, Journal of Materials Processing Technology, 206, 132–142.

[18]. Threadgill, P.L. (1999). Friction-Stir Welding-State of the Art, TWI, Report 678, England,

[19]. Bradly, G.R., and James, M.N. Geometry and Microstructure of Metal Inert Gas and Friction Stir Welded Aluminum Alloy 5383-H321, Report, and Oct.2000.

[20]. Rai, R., De, A., Bhadeshia H.K.D.H. & Debroy, T. (2011), Review: Friction stir welding tools, Science and Technology of Welding and Joining, Vol. 16, No. 4, p. 325.

[21]. Zhao, Y. H., Lin, S. B., Wu, L., and Qu, F.X. (2005). The influence of pin geometry on bonding and mechanical properties in friction stir weld 2014 Al alloy. Materials Letters 59: 2948–2952.

[22]. Hidetoshi, F., Ling, C., Masakatsu, M., Yutake, S. S., and Kiyoshi, N. (2006). Effect of threads on tool in friction stir welding of aluminium alloys. Materials Science Forum 512: 389–394.

[23]. G. Padmanaban, V. Balasubramanian, (2009). Selection of FSW tool pin profile, shoulder diameter and material for joining AZ31B magnesium alloy – An experimental approach, Materials and Design, 30, 2647–2656.

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Research Paper

Preparation and Characterisation of Rare Earth Doped Phosphate Glasses

Manpreet Kaur* , Mehak Mahajan, Mohini Bhatia, Sarabjit Kaur, Lakhwant Singh

--- Department of Physics, DAV College, Amritsar, India.

* Department of Physics, GNDU, Amritsar, India

Kaur, M., Mahajan, M., Bhatia, M., Kaur, S., & Singh, L. (2014). Preparation and Characterisation of Rare Earth Doped Phosphate Glasses. i-manager's Journal on Material Science, 2(1), 15-19. https://doi.org/10.26634/jms.2.1.2759

Abstract

Phosphate glasses with composition 50P₂O₅-30CaO-(20-x) Li₂O-xCeO₂ with x varying from 0-2.0 mol % were prepared using the conventional melt quench technique. The amorphous nature of prepared glasses was confirmed from the XRD(X-Ray Diffraction) spectra. The density and Molar volume of the glasses was found using the Archimedes principle. The value of the density lies in the range of 3.58-3.71 g/cm³ . The density of the prepared glasses was found to increase with the concentration of CeO₂ . This was explained as the molecular weight of CeO₂ is more as compared to the molecular weight of Li₂O. The Raman spectra was obtained for the prepared glass samples and it was found that no new peaks are formed with the doping of CeO₂ , and only there is a change in the intensity of peaks and the peaks are red shifted. The bandgap energy is found to decrease with CeO₂ doping due to the formation of more NBOs.

References

[1]. R. K. Brow, (2000). "Structure of Simple Phosphate Glasses," J. Non-Cryst. Solids, 263-264, 1-28 .

[2]. Babita Tiwari, V. Sudarsan, Anupam Dixit, and Govind P. Kothiyal, (2011). "Effect of TiO2 Addition on the Optical, Thermo-Physical and Structural Aspects of Sodium Alumino- Phosphate Glasses," J. Am. Ceram. Soc.,1-7 .

[3]. K. V. Shah, M. Goswami, M. N. Deo, A. Sarkar, S. Manikandan, V. K. Shubhande, and G. P. Kothiyal, (2006). "Effect of B2O3 Addition on Microhardness and Structural features of 40Na2O-10BaO-xB2O3-(50- x) P2O5 Glass System," Bulletin of Material Science, 29 .

[4]. Steve W. Martin, (1991). "Ionic Conduction in Phosphate Glasses," J. Am. Ceram. Soc., 74, 1767-84 .

[5]. V. Nazabal, E. Fargin, C. Labrugere, and G. Le. Flem, (2000). "Second Harmonic Generation Optimisation in Thermally Poled Borophosphate Characterisation by XANES and XPS,"J. Non-Cryst. Solids, 270, 223-33

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[12]. Dheeraj Jain, V Sudarsan, RK Vatsa , CGS Pillai, (2009). "Luminescence studies on ZnO-P2O5 glasses doped with Gd2O3:Eu nanoparticles and Eu2O3" J. of Luminescence, 129, 439-443.

[13]. K. Venkata Rao, YC Ratnakaram, M Seshadri, JL Rao, (2010). "Optical and Luminescence studies of Pr3+ and Er3+ doped different phosphate glasses," Physica B, 405, 2297-230.

[14]. Jincheng Du, Leopold Kokou, Jennifer L. Rygel, Yongsheng Che, Carlo G. Pantano, (2011). "Structure of Cerium Phosphate Glasses : Molecular Dynamics simulation," J. Am. Ceram. Soc., 94 [8], 2393- 2401.

[15]. Jennifer L, Yongsheng Che, Rygel, Carlo G. Pantano, Tomohiro Shibata, Jincheng Du, Leopold Kokou, (2011). "Local Structure of Cerium in Aluminophophate and Silicophophate Glasses,"J. Am. Ceram. Soc., 94 [8], 2442- 2451.

[16]. MA Marzouk, HA ElBatal, AM Abdel Ghany, FM Ezz Eldin, (2011). "Ultraviolet, visible, ESR, and Infrared spectroscopic studies of CeO2 doped lithium phosphate glasses and effect of gamma irradiation" J. Molecular Structure, 997, 94-102.

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Research Paper

Transport Properties Of Metallic Nanowires On Silicon Substrate

Jaskiran Kaur* , Surinder Singh**

*-** Department of Physics, Guru Nanak Dev University, Amritsar, India.

Kaur, J., & Singh, S. (2014). Transport Properties of Metallic Nanowires on Silicon Substrate. i-manager's Journal on Material Science, 2(1), 20-23. https://doi.org/10.26634/jms.2.1.2760

Abstract

This paper presents the electrical properties of the randomly distributed metallic (Co, Ni and Fe) nano/micro wires on Silicon. Deposition was carried out potentiostatically into the pores of the track-etch polycarbonate membrane spin coated onto the Silicon substrate. Spin coated films were irradiated with 150MeV Ni (+11) ions at a fluence of 8E7 2 ions/cm , followed by UV irradiation and chemically etching in aqueous NaOH (6N, at room temperature). Later morphological, and electrical properties of the so deposited nano-/micro structures were studied.

References

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Research Paper

PMMA Based Polymer Gel Electrolyte Containing LiCF₃SO₃

Narinder Arora* , Ajay Sharma, Amit Kumar*, Rajesh Kumar****

- Assistant Professor, Department of Physics, D.A.V. College, Amritsar, India.

- PG Scholar, Department of Physics, D.A.V. College, Amritsar, India.

Arora, N., Sharma, A., Kumar, A., & Kumar, R. (2014). PMMA Based Polymer Gel Electrolyte Containing LiCF₃SO₃. i-manager's Journal on Material Science, 2(1), 24-26. https://doi.org/10.26634/jms.2.1.2761

Abstract

Effect of polymer (PMMA) and salt (LiCF₃SO₃ ) on the conducting behaviour of polymer gel electrolytes in non-volatile solvent (PC) has been studied. The maximum ionic conductivity ( = 2.92 mS/cm) of polymer gel electrolyte has been observed at room temperature. An anomalous conducting behaviour is observed at small content of PMMA addition in gel electrolyte. Small increase in conductivity observed with increasing temperature (range 10^o -70^o C) is in factor-wise only, which makes these gel electrolytes suitable for many device applications.

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Review Paper

Importance of Post Curing and Radiation Assisted Post Curing for Fiber Reinforced Polymer Composites – A Review

Kiran Kumar P.*

* Professor, Department of Mechanical Engineering, S.J.B Institute of Technology, Bangalore, Karnataka, India.

Kumar, P. K. (2014). Importance of Post Curing and Radiation Assisted Post Curing For Fiber Reinforced Polymer Composites-A Review. i-manager's Journal on Material Science, 2(1), 27-37. https://doi.org/10.26634/jms.2.1.2762

Abstract

FRP composites have been the part and parcel of many industrial and domestic applications. It is not only limited to aerospace, though the roots are from aerospace there is a paradigm shift in methods and applications. It covers wide range of products from headgear to aircrafts. Post curing leads to improved properties due to better interfacial bonding between matrix and fiber. Maximum amount of time is consumed in post curing of polymer composites. In this paper alternate method particularly radiation post curing is discussed in detail. Comparison between thermal curing with IR and other radiation curing methods is reviewed.

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i-manager's Journal on Material Science (JMS)

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Volume 2 Issue 1 April - June 2014

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Preparation and Characterisation of Rare Earth Doped Phosphate Glasses

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Transport Properties Of Metallic Nanowires On Silicon Substrate

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PMMA Based Polymer Gel Electrolyte Containing LiCF3SO3

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Importance of Post Curing and Radiation Assisted Post Curing for Fiber Reinforced Polymer Composites – A Review

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* Professor, Department of Mechanical Engineering, S.J.B Institute of Technology, Bangalore, Karnataka, India.

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Surbhi Sharma* , Amit Sarin, Navjeet Sharma*

* Research Scholar, Punjab Technical University, Kapurthala, India

Department of Physics, Amritsar College of Engineering & Technology, Amritsar, India

* Department of Physics, DAV College, Jalandhar, India

Manpreet Kaur* , Mehak Mahajan, Mohini Bhatia, Sarabjit Kaur, Lakhwant Singh

--- Department of Physics, DAV College, Amritsar, India.

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- PG Scholar, Department of Physics, D.A.V. College, Amritsar, India.

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