i-manager Publications

Effect of Addition of Transition Metal Oxides on the Optical and Structural Properties of Phosphate Glasses

Manpreet Kaur*

*Assistant Professor, Department of Physics, DAV College, Amritsar, Punjab, India.

Periodicity:January - March'2016
DOI : https://doi.org/10.26634/jms.3.4.4824

Abstract

Phosphate glasses having composition 50P₂O₅–30MgO–20Na₂O and 50P₂O₅–30MgO–15Na₂O-5TMO (with TMO(Transition Metal Oxides) as CuO, Fe₂O₃ and TiO₂ ) were prepared using conventional melt quench technique and were characterized for their optical and structural properties. The absence of any sharp peak in the XRD spectra confirmed the amorphous behaviour of prepared glasses. Density of prepared glasses was found in the range of 2.51-2.62 g/cm³ . The FTIR (Fourier Transform Infrared Spectroscopy) spectra of the glasses only showed a variation in the intensity of peaks with doping of different transition elements. The band gap energy and refractive index were calculated from the UVVisible optical absorption spectra in the wavelength range of 200-900 nm. It was found that, the band gap energy was maximum for host glass (3.37 eV) and minimum for CuO doped glass samples (3.21 eV). SEM (Scanning Electron Microscope) morphology also showed the lack of any long range periodicity in the prepared glass samples.

Keywords

Phosphate Glass, XRD, FTIR, Band Gap, SEM.

How to Cite this Article?

Kaur, M. (2016). Effect of Addition of Transition Metal Oxides on the Optical and Structural Properties of Phosphate Glasses. i-manager’s Journal on Material Science, 3(4), 20-27. https://doi.org/10.26634/jms.3.4.4824

References

[1]. ElBatal, F.H., Marzouk, M.A., & Abdelghany, A.M. (2011), “UV-visible and infrared absorptions spectra of gamma irradiated V₂O_5^-doped in sodium phosphate, lead phosphate, zinc phosphate glasses: A comparative study”. Journal of Non Crysalline Solids, Vol. 357(3), pp 1027-31.

[2]. Brow, R.K. (2000), “Review: The Structure of Simple Phosphate Glasses”. Journal of Non Crysalline Solids, Vol. 263, pp. 264 1-28.

[3]. ElBatal, F.H. (2208). “Gamma ray Interaction with copper-doped sodium phosphate galsses”. Journal of Material Science, Vol. 43(3), pp.1070-79.

[4]. Tiwari, B., Sudarsan, V., Dixit, A., Kothiyal, G.P. (2011), “Effect of TiO₂ addition on optical, thermo-physical and structural Aspects of sodium alumino-phosphate glasses”. Journal of American Ceramic Society, Vol. 94(5), pp. 1440- 43.

[5]. Behrends, F., & Eckert, H. (2011), “Mixed Alkali Effects in Aluminophosphate Glasses: A Re-rxamination of the system [xNa₂O(1-x)LiO₂]_.46 [yAl₂O₃(1-y)P₂O₅]_.54 ”. The Journal of Physical Chemistry, Vol. 115, pp. 17175-79.

[6]. Ahmed, J., Lewis, M., & Knowles, J.C. (2004), “Phosphate glasses for tissue engineering : Part 1.Processing and characterization of a ternary based P₂O₅-Cao-Na₂O glass system,” Biomaterials, Vol. 25, pp. 491-94.

[7]. Ravikumar, R.V.S.S.N., Reddy, V.R., Chandrasekhar, A.V., Reddy, B.J., Reddy, Y.P., & Rao, P.S. (2002), “Tetragonal site of transition metal ions doped sodium phosphate glasses”. Journal of Alloys and Compounds, Vol. 337(1), pp. 272-76.

[8]. Ravikumar, R.V.S.S.N., Yamauchi, J., Chandrasekhar, A.V., Reddy, Y.P., & Rao, P. S. (2005), “Identification of chromium and nickel sites in zinc phosphate glasses”. Journal of Molecular Structure, Vol. 740, No. 1, pp. 169- 173.

[9]. Bunker, B.C., Arnold, G. W., & Wilder, J. A. (1984), "Phosphate Glass Dissolution in Aqueous Solutions". Journal of Non-Crystalline Solids, Vol. 64, pp. 291-94.

[10]. Bingham, P.A., Hand, R.J., Hannat, O.M., Forder, S.D., & Kilcoyne, S.M. (2009), “Effects of modifier additions on the thermal properties, chemical durability, Oxidation state and structure of iron phosphate glasses”. Journal of Non- Crystalline Solids, Vol. 355, pp. 1526-29.

[11]. Sahar, M.R., & Kamaruddin N. (1996), “The phase - - equilibrium of binary MgO and CaO phosphate glasses”. Journal of Material Science Letters, Vol. 15, 1932.

[12]. Shelby, J.M. (2000), “Properties of alkali-alkaline earth metaphosphate glasses”. Journal of Non-Crystalline Solids, Vol. 263-264, pp. 271-74.

[13]. ElBatal, F.H., Abo Naf, S.M., & Ezz ElDin F.M., (2005), “Spectroscopic studies of gamma-irradiated transition metals-doped soda lime phosphate glass”. Indian Journal of Pure Applied Physics, Vol. 43(8), pp. 579-83.

[14]. Marzouk, S.Y., Elalaily, N.A., Ezz-Eldin, F.M., & Abd- Allah, W.M., (2006), “Optical absorption of gammairradiated lithium-borate glasses doped with different transition metal oxides”. Physica B, Vol. 382, pp. 340-43.

[15]. Jain, R.K., & Lind, R.C. (1983), “Degenerate four-wave mixing in semiconductor-doped glasses”. Journal of Optical Society American, Vol. 73, pp. 647-49.

[16]. Montagne, L., Palavit, G., & Mairesse, G. (1996), “31 P MAS NMR and FTIR analysis of (50-x)Na₂O-xBi₂O₃ -(50-x/2)P₂O₅ glasses”. Physics Chemistry Glasses, Vol. 37(5), (1996) 206.

[17]. Abo-Naf, S.M., El-Amiry, M.S., & Abdel-Khalek, A.A. (2008), “FT-IR and UV–Vis optical absorption spectra of ?- irradiated calcium phosphate glasses doped with Cr₂O₃, V₂O₅ and Fe₂O₃ ”. Optical Materials, Vol. 30(6), pp. 900-03.

[18]. ElBatal, H.A., ElMandouh, Z.E., Zayed, H.A., Marzouk, S.Y., Elkomy, G.M., & Hosny, A., (2013), “Gamma rays interaction with copper doped lithium phosphate glasses”. Journal of Molecular Structure, Vol. 1054-055, pp. 57-60.

[19]. Abdelghany, A.M., ElBatal, F.H., Azzoz, M.A., Ouis, M.A., & ElBatal, H.A. (2012), “Optical and infrared absorption spectra of 3D transition metal ions doped sodium borophosphate glasses and effect of gamma irradiation”. Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy, Vol. 98, pp. 148-51.

[20]. Giridhar, G., Sastry, S.S., & Rangacharyulu, M., (2011), “Spectroscopic studies on Pb₃O₄-ZnO-P₂O₅ glasses doped with transition metal ions”. Physica B, Vol. 406, pp. 4027-30.

[21]. Moustafa, Y.M., & Egili, K.E. (1998), “Infrared spectra of sodium phosphate glasses”. Journal of Non-Crystalline Solids, Vol. 240, pp. 144-46.

[22]. ElBatal, F.H., Hamdy, Y.M., & Marzouk, S.Y. (2009), “UV–visible and infrared absorption spectra of transition metals-doped lead phosphate glasses and the effect of gamma irradiation”. Journal of Non-Crystalline Solids, Vol. 355 (50-51), pp. 2439-41.

[23]. Bae, B.S., & Weinberg, M.C., (1994), “Optical absorption of copper phosphate glasses in the visible spectrum”. Journal of Non-Crystalline Solids, Vol.168, pp. 223-26.

[24]. F.H. ElBatal, (2009), “UV-Visible, Infrared, Raman and ESR spectra of gamma irradiated TiO₂ doped soda lime phosphate glasses”. Indian Journal of Pure and Applied Physics, Vol. 47, pp. 631-34.

Effect of Addition of Transition Metal Oxides on the Optical and Structural Properties of Phosphate Glasses

Abstract

Keywords

How to Cite this Article?

References

If you have access to this article please login to view the article or kindly login to purchase the article

Purchase Instant Access

Options for accessing this content:

	North Americas,UK, Middle East,Europe		India	Rest of world
	USD	EUR	INR	USD-ROW
Pdf	35	35	200	20
Online	35	35	200	15
Pdf & Online	35	35	400	25