Preparation and Characterization of Long Persistence Strontium Aluminate Phosphor

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*Professor, Department of Applied Physics, Faculty of Engineering and Technology, SSGI, Shri Shankaracharya Technical Campus, Junwani, Bhilai (C.G.), India
Periodicity:October - December'2014
DOI : https://doi.org/10.26634/jms.2.3.2965

Abstract

The present paper reports the synthesis of SrAl2O4:Eu2+ , Dy3+ long persistent nano phosphor by combustion method using urea as reducer at 650°C. Crystallization, particles size and luminescence properties of the sample have been investigated. It is found' that the average size of particle is nano to micrometer. The emission spectra are broad bands with the peaks at 520 nm, respectively. The persistent luminescence phenomenon involves the formation of traps followed by thermal bleaching of traps and the characteristic Eu2+ emission as well as the nature of traps and the persistent time is 10 times longer than that of traditional sulfide phosphors . Absorption spectra and XRD have been used to characterize the synthesized phosphor.

Keywords

SrAl O ; Photoluminescence; Nanophosphor; Long Persistence; Photoluminescence; After Glow.

How to Cite this Article?

Patel, R. P. (2014). Preparation and Characterization of Long Persistence Strontium Aluminate Phosphor. i-manager's Journal on Material Science, 2(3), 27-30. https://doi.org/10.26634/jms.2.3.2965

References

[1]. Matsuzawa T., Aoki Y., Takeuchi N. & Murayama Y (1996). “A new long phosphorescent phosphor with high brightness SrAl2O4 : Eu2+ , Dy3+ ”. J. Electrochem. Soc., Vol.143 (8), pp. 2670– 2673.
[2]. Luitel H. N. (2010). “Preparation and properties of long persistent Sr4Al14O25 phosphors activated by rare earth metal ions”: Ph. D. thesis, Saga University.
[3]. Sharma Suchinder K., Pitale Shreyas S., Malik M. Manzar, Rao T. K. Gundu., Chawla S., Qureshi M.S., & Dubey R.N. (2010). “Spectral and defect analysis of Cudoped combustion synthesized new SrAl4O7 phosphor”. J. of Lumin. 130(2), 240-248.
[4]. Nag A.& Kutty T.R.N. (2003). “Role of B2O3 on the phase stability and long phosphorescence of SrAl2O4 : Eu2+ , Dy3+'' ”. J. Alloys Comp. Vol. 354 (1-2), pp. 221-231.
[5]. Yuan Z. X., Chang C. K., Mao D. L. & Ying W. (2004). “Effect of composition on the luminescent properties of Sr4Al14O25 :Eu2+ , Dy3+ phosphors”. J. Alloys Comp. Vol. 377(1-2), pp. 268–271.
[6]. Chang C., Yuan Z. & Mao D. (2006). “Eu2+ activated long persistent strontium aluminate nano scaled phosphor prepared by precipitation method”. J. Alloys Comp., Vol. 415( 1-2), pp. 220–224.
[7]. Peng M., Pei Z., Hong G., & Su Q., (2003). “Study on the reduction of Eu3+ fi Eu2+ in Sr4Al14O25 : Eu prepared in air atmosphere”, Chemical. Phys. Lett. Vol. 371, pp. 1–6.
[8]. Han S.D., Singh K. C., Cho T. Y. et al. (2008). “Preparation and characterization of long persistence strontium aluminate phosphor”. J. Lumin, Vol. 128(3), pp. 301–305.
[9]. Li Q., Zhao J & Sun F.(2010). “Energy transfer mechanism of Sr2Al14O25 :Eu2+ phosphor”. J. Rare Earths, Vol. 28(1), pp. 26–29.
[10]. Danuta Dutczak, Cees Ronda, Andries Meijerink & Thomas Jüstel (2013). “Red luminescence and persistent luminescence of Sr3Al2O5Cl2:Eu2+ ,Dy3+'' ”. J. Lumin, 141, pp. 150-154.
[11]. Sharma Pooja , Haranath D., Chander Harish , Singh Sukhvir (2008). “Green Chemistry-mediated synthesis of nanostructures of afterglow phosphor”. App. Surf. Sci. Vol. 254 (2008), pp. 4052–4055.
[12]. Shafia E., Aghaei A., Davarpanah A., Bodaghi M., Tahriri M. and Alavi S. H. (2011). “Synthesis and Characterization of SrAl2O4:Eu2+ , Dy3+ Nanocrystalline Phosphorescent Pigments”. Trans. Ind. Ceram. Soc., Vol. 70 (2), pp. 71-77.
[13]. Yu X., Zhou C., He X., Peng Z., Yang S., (2004). “The influence of some processing conditions on luminescence of SrAl2 O4 : Eu2+ nanoparticles produced by combustion method”. Mater, Lett. 58, pp. 1087–1091.
[14]. Zhao, C.,& Chen, D., [2007]. “Synthesis of CaAl2O4: Eu, Nd long persistent phosphor by combustion processes and its optical properties”. Mater. Lett. Vol. 61, pp. 3673- 3675.
[15]. Gyori Z., Havasi V., Madarász D., Tátrai D., Brigancz T., Szabó G, Kónya Z., Kukovecz A., (2013). “Luminescence properties of Ho3+ co-doped SrAl2O4 :Eu2+ , Dy3+ long”- persistent phosphors synthesized with a solid-state method . J. Molecular Struct Vol. 1044, pp. 87–93.
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