The thermal stability of the high-pressure phase 8-coordination of oxygen in Cerium-doped Strontium oxide (SrO:Ce) phosphors was investigated in this study. Due to the tendency of Strontium oxides 6-coordination of oxygen to react with moisture, high thermal and chemical stability is required for commercial applications. Eight-coordinated SrO:Ce phosphors were synthesized by sintering in a reducing atmosphere, and their thermal stability was examined using X-ray diffraction (XRD), photoluminescence (PL), cathodoluminescence (CL), and X-ray photoelectron spectroscopy (XPS). The results show that the eight-coordinated SrO:Ce phosphors exhibit high thermal stability, particularly after annealing. This is expected to contribute to the development of new fluorescent materials with Ce3+ as the luminescent center.