Synthesis of SrBaFexMo2-xO6 (X=1.0, 1.1, 1.3 and 1.4) Double Perovskites by Sonication: Characterization and Electron Spin Resonance Studies

S. Varaprasad*, G. Laxminarayana**, M. Ramana***, A. Ramachander Rao****, L. Koteswara Rao*****
* Electro-Optical Instrument Research Academy, Vignyanakancha, Hyderabad, Telangana, India.
**-**** Research Centre Imarat, Vignyanakancha, Hyderabad, Telangana, India.
***** Koneru Lakshmaiah University, Hyderabad, Telangana, India.
Periodicity:April - June'2022

Abstract

This paper presents influence of ultrasound-assisted method on structure, tolerance factor, density and Electron spin resonance studies of SrBaFexMo2-xO6 (x = 1.0, 1.1, 1.3 and 1.4) (SBFMO) double perovskite. SrBaFexMo2-xO6 double perovskite was synthesized by sonochemical procedure at low temperature (9500C) under Ar/ H2 atmosphere. X-ray diffraction studies revealed a single phase with a cubic crystal structure for all the samples. The existence of all elements (Sr, Ba, Fe, Mo, O) contamination-free in the required percentage in SBFMO compound has been analyzed by Energy Dispersive X-ray Spectroscopy (EDS). Goldschmidt Tolerance factor 't' has been used to quantitatively predict the stability and closeness of A2BxB12-xO6. Density measurements for all samples of SrBaFexMo2-xO6 (x = 1.0, 1.1, 1.3 and 1.4) were done both theoretically and experimentally. Electron Spin Resonance (ESR) spectra of SrBaFexMo2-xO6 (x = 1.0, 1.1, 1.3 and 1.4) were studied to determine the iron state in the compound by varying magnetic field at a constant frequency (X-Band).

Keywords

Double Perovskite, Sonochemical, Characterization, Magnetic Properties.

How to Cite this Article?

Varaprasad, S., Laxminarayana, G., Ramana, M., Rao, A. R., and Rao, L. K. (2022). Synthesis of SrBaFexMo2-x O6 (X=1.0, 1.1, 1.3 And 1.4) Double Perovskites by Sonication: Characterization and Electron Spin Resonance Studies. i-manager’s Journal on Material Science, 10(1), 1-8.

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