Synthesis, Characterization and Optical Parameters Studies of Novel Cu(II) Complexes with Various Ligands

Dhara D. Patel*, Mohsinali Rabadi**, Smit Sathvara***
*-** Department of Chemistry, Smt. S. S. Patel Nootan Science & Commerce College, Visnagar, Gujarat, India.
*** Department of Chemistry, Sankalchand Patel University, Visnagar, Gujarat, India.
Periodicity:January - March'2022
DOI : https://doi.org/10.26634/jms.9.4.18548

Abstract

Cu(II) complexes were prepared using p-dimethylaminobenzaldehyde, alpha-naphthylamine, and diphenylamine. Elemental analysis, measurements of conductivity and magnetic susceptibility, as well as spectroscopic (IR and UV) and thermal studies (e.g., TGA) were used to describe transition metal complexes. Various spectrum data are used to characterize all of the complexes. In addition, optical absorption is used to determine absorbance, absorption coefficient, refractive index, transmission, band gap, and permittivity. Visual constants were calculated by using UV-Vis spectroscopy. Magnetic, electronic spectral and TG studies suggest the geometry of all complexes. Optical studies suggest the behavior of these various complexes. Various properties of Cu(II) complexes have been estimated by different methods of calculation.

Keywords

Band Gap, Dielectric Constant, Refractive Index, UV-Vis Spectroscopy.

How to Cite this Article?

Patel, D. D., Rabadi, M., and Sathvara, S. (2022). Synthesis, Characterization and Optical Parameters Studies of Novel Cu(II) Complexes with Various Ligands. i-manager’s Journal on Material Science, 9(4), 16-22. https://doi.org/10.26634/jms.9.4.18548

References

[1]. Ahmed, A. H., Hassan, A. M., Gumaa, H. A., Mohamed, B. H., Eraky, A. M., & Omran, A. A. (2019). Copper(II)-oxaloyldihydrazone complexes: Physicochemical studies: Energy band gap and inhibition evaluation of free oxaloyldihydrazones toward the corrosion of copper metal in acidic medium. Arabian Journal of Chemistry, 12(8), 4287-4302. https://doi.org/10.1016/j.arabjc.2016.05.015
[2]. Ahmed, A., & Lal, R. A. (2017). Synthesis, characterization and electrochemical studies of copper(II) complexes derived from succinoyl- and adipoyldihydrazones. Arabian Journal of Ahemistry, 10, S901-S908. https://doi.org/10.1016/j.arabjc.2012.12.026
[3]. Bäck, L. G., Ali, S., Karlsson, S., Wondraczek, L., & Jonson, B. (2019). X-ray and UV-Vis-NIR absorption spectroscopy studies of the Cu(I) and Cu(II) coordination environments in mixed alkali-lime-silicate glasses. Journal of Non-Crystalline Solids: X. 3, Article 100029. https://doi.org/10.1016/j.nocx.2019.100029
[4]. Bouaamlat, H., Hadi, N., Belghiti, N., Sadki, H., Naciri Bennani, M., Abdi, F., & Abarkan, M. (2020). Dielectric properties, AC conductivity, and electric modulus analysis of bulk ethylcarbazole-terphenyl. Advances in Materials Science and Engineering, 2020, Article 8689150. https://doi.org/10.1155/2020/8689150
[5]. Chen, H., Ran, L., Huangfu, J., Zhang, X., Chen, K., Grzegorczyk, T. M., & Kong, J. A. (2004). Left-handed materials composed of only S-shaped resonators. Physical review E, 70(5), Article 057605. https://doi.org/10.1103/PhysRevE.70.057605
[6]. Crocker, J. F. S., & Safe, S. (1981). Identification of a toxic impurity in commercial diphenylamine. Journal of Environmental Science and Health, Part B, 16(2), 125- 130. https://doi.org/10.1080/03601238109372245
[7]. Demir, I., Diler, S. B., & Uçan, S. Y. (2020). Synthesis, characterzation, and genetoxic effect of some novel schiff base–metal complexes. Russian Journal of General Chemistry, 90(6), 1051-1054. https://doi.org/10.1134/S1070363220060183
[8]. Dhanaraj, C. J., & Nair, M. S. (2009). Synthesis and characterization of metal (II) complexes of poly (3- nitrobenzylidene-1-naphthylamine-co-succinic anhydride). European Polymer Journal, 45(2), 565-572. https://doi.org/10.1016/j.eurpolymj.2008.11.011
[9]. Finny, C. S. L., & Sudhakar, A. (2019). Synthesis, characterization and antimicrobial studies of copper(II) and vanadium(IV) complexes with n-(3-nitrobenzylidene)- 1-naphthylamine. International Journal of Research and Scientific Innovation (IJRSI), 6(12), 29–40.
[10]. Gupta, R., & Kaplan, S. G. (2003). High accuracy ultraviolet index of refraction measurements using a Fourier transform spectrometer. Journal of Research of the National Institute of Standards and Technology, 108(6), 429-437. https://doi.org/10.6028/jres.108.037
[11]. Kokoszka, G. F., & Duerst, R. W. (1970). EPR studies of exchange coupled metal ions. Coordination Chemistry Reviews, 5(2), 209-244. https://doi.org/10.1016/S0010-8545(00)80136-8
[12]. Kokoszka, G. F., Linzer, M., & Gordon, G. (1968). Electron paramagnetic resonance spectra of polycrystalline dimeric complexes. Copper propionate monohydrate and zinc-doped copper propionate monohydrate. Inorganic Chemistry, 7(9), 1730-1735. https://doi.org/10.1021/ic50067a007
[13]. Parsaee, Z., Haratipour, P., Lariche, M. J., & Vojood, A. (2018). A novel high performance nano chemosensor for copper (II) ion based on an ultrasound-assisted synthesized diphenylamine-based Schiff base: Design, fabrication and density functional theory calculations. Ultrasonics Sonochemistry, 41, 337-349. https://doi.org/10.1016/j.ultsonch.2017.09.054
[14]. Saad, I. Ben, Hannachi, N., Roisnel, T., & Hlel, F. (2019). Optical, UV-Vis spectroscopy studies, electrical and dielectric properties of transition metal-based of the novel organic-inorganic hybrid (C6H10N2) (Hg2Cl5)2.3H2O. Journal of Advanced Dielectrics, 9(5), 1-15. https://doi.org/10.1142/S2010135X19500401
[15]. Shanty, A. A., Raghu, K. G., & Mohanan, P. V. (2019). Synthesis, characterization: Spectral and theoretical, molecular docking and in vitro studies of copper complexes with HIV RT enzyme. Journal of Molecular Structure, 1197, 154-163. https://doi.org/10.1016/j.molstruc.2019.06.097
[16]. Syaima, H., Rahardjo, S. B., & Suciningrum, E. (2018). Synthesis and characterization of a coordination complex of Tetrakis (diphenylamine) copper(II) Sulfate Hexahydrate. IOP Conference Series: Materials Science and Engineering, 333, Article 012003. https://doi.org/10.1088/1757-899X/333/1/012003
[17]. Vigato, P. A., & Tamburini, S. (2004). The challenge of cyclic and acyclic Schiff bases and related derivatives. Coordination Chemistry Reviews, 248(17-20), 1717-2128. https://doi.org/10.1016/j.cct.2003.09.003
If you have access to this article please login to view the article or kindly login to purchase the article

Purchase Instant Access

Single Article

North Americas,UK,
Middle East,Europe
India Rest of world
USD EUR INR USD-ROW
Pdf 35 35 200 20
Online 35 35 200 15
Pdf & Online 35 35 400 25

Options for accessing this content:
  • If you would like institutional access to this content, please recommend the title to your librarian.
    Library Recommendation Form
  • If you already have i-manager's user account: Login above and proceed to purchase the article.
  • New Users: Please register, then proceed to purchase the article.