Synthesis of a Moringa Based Coagulant Functionalized by Iron Oxide Nanoparticles

Felistas Gwaindepi *, Itai Mutadza **
*-** Department of Chemical and Process Systems Engineering, Harare Institute of Technology, Zimbabwe.
Periodicity:January - June'2020
DOI : https://doi.org/10.26634/jchem.2.1.17220

Abstract

Currently, Zimbabwe as a whole has been facing economic challenges in various ways, and this has greatly affected the functionality of quite a number of industries. Taking into consideration of the water treatment industries, mainly all city councils have been facing difficulties in meeting the potable water demand due to lack of funds to purchase the highly expensive chemicals required for raw water treatment. This research serves to provide an alternative to the coagulant used in most water treatment facilities in Zimbabwe, with reference to the City of Gweru. A moringa based coagulant functionalized by iron oxide nanoparticles was synthesized consisting of a ratio of moringa seed extract and iron oxide nanoparticles in a ratio of 3:1. In addition to the economic benefits of the moringa based coagulant, it is also environmentally friendly. The amount of non-biodegradable sludge resulting from the use of aluminium sulphate can be reduced. The synthesized coagulant is partly organic due to the presence of the moringa seed extract, making it biodegradable. It also has magnetic properties due to the presence of the iron oxide nanoparticles. These can be separated easily from the organic part of the sludge through application of a magnetic field and reused again in the synthesis of the coagulant or for other purposes. Jar test experiments were carried out to determine the optimum dosage of the moringa based coagulant and also to compare properties of water treated with the magnetic coagulant to water treated with aluminium sulphate and moringa seed extract separately. The magnetic coagulant gave the best results with a minimum dosage of 45 mg/L. A turbidity removal of 91.5% and a pH of 7.04 was observed.

Keywords

Magnetic Coagulant, Moringa, Aluminium Sulphate, Turbidity, Iron Oxide Nanoparticles.

How to Cite this Article?

Gwaindepi, F., and Mutadza, I. (2020). Synthesis of a Moringa Based Coagulant Functionalized by Iron Oxide Nanoparticles. i-manager's Journal on Chemical Sciences, 2(1), 11-20. https://doi.org/10.26634/jchem.2.1.17220

References

[3]. Ahuja, S. (Ed.). (2013). Monitoring water quality: Pollution assessment, analysis, and remediation. Amsterdam: Elsevier.
[4]. Ali, A., Zafar, H., Zia, M., ul Haq, I., Phull, A. R., Ali, J. S., & Hussain, A. (2016). Synthesis, characterization, applications, and challenges of iron oxide nanoparticles. Nanotechnology, Science and Applications, 9, 49-67.
[6]. Bichi, M. H., Agunwamba, J. C., & Muyibi, S. A. (2012). Kinetics of water disinfection with Moringa oleifera seeds extract. Journal of Environment and Earth Sciences, 2(7), 58-68.
[7]. Choy, S. Y., Prasad, K. M. N., Wu, T. Y., Raghunandan, M. E., & Ramanan, R. N. (2014). Utilization of plant-based natural coagulants as future alternatives towards sustainable water clarification. Journal of Environmental Sciences, 26(11), 2178-2189.
[8]. Dempsey, B. A., & O'Melia, C. R. (1984). Removal of naturally occurring compounds by coagulation and sedimentation. Critical Reviews in Environmental Control, 14(4), 311-331.
[9]. Diaz, A., Rincon, N., Escorihuela, A., Chacin, F. N., & Forster, C. F. (2013). A preliminary evaluation of water quality parameters after coagulation by natural coagulants. Process Biochemistry, 35(3-4), 391-395.
[10]. Edzawald, J. K., & Van Bencschoten, J. E. (2008). Aluminium coagulation of natural organic matter. Chemical Water and Wastewater Treatment, 8(1), 58-63.
[11]. Howe, K. J., Hand, D. W., Crittenden, J. C., Trussell, R. R., & Tchobanoglous, G. (2012). Principles of water treatment. John Wiley & Sons.
[12]. Jahn, S. A. A. (1986). Proper use of African natural coagulants for rural water supplies: Research in the Sudan and a guide for new projects. Eschborn, Germany: Deutsche Gesellschaft für Technische Zusammenarbeit.
[14]. Kandpal, N. D., Sah, N., Loshali, R., Joshi, R., & Prasad, J. (2014). Co-precipitation method of synthesis and characterization of iron oxide nanoparticles. Journal of Scientific and Industrial Research (JSIR), 73 (2), 87-90.
[15]. Lassoued, A., Dkhil, B., Gadri, A., & Ammar, S. (2017). Control of the shape and size of iron oxide (α-Fe2O3) nanoparticles synthesized through the chemical precipitation method. Results in Physics, 7, 3007-3015.
[17]. Lee, S. J., Jeong, J. R., Shin, S. C., Kim, J. C., & Kim, J. D. (2004). Synthesis and characterization of super paramagnetic maghemite nanoparticles by the coprecipitation technique. Journal of Magneitism and Magnetic Materials, 63(1-2), 147-150.
[20]. Olagbemide, P. T., & Philip, C. N. A. (2014). Proximate analysis and chemical composition of raw and defatted Moringa oleifera kernel. Advances in Life Science and Technology, 24, 92-99.
[21]. Ramimoghadam, D., Agheri, S. and Hamid, S.B.A. (2014). Progress in electrochemical synthesis of magnetic iron oxide nanoparticles. Journal of Magnetism and Magnetic Materials, 368, 207-229.
[22]. Samuel, M. S., Bose, L., & George, K. C. (2009). Optical properties of ZnO nanoparticles. SB Academic Review, 16(1 & 2), 57-65.
[23]. Teia, A. S., & Koh, P.Y. (2009). Synthesis, properties and applications of magnetic iron oxide nanoparticles. Progress in Crystal Growth and Characterization of Materials, 45(7), 356-399.
[24]. Viessman, W., Hammer, M. J., Perez, E. M., & Chadik, P. A. (2003). Water supply and pollution control. Water Science and Technology, 7(1), 257-275.
[25]. Wassana, H. M., Perera, G. D., Gunawardena, P. S., & Bandara, J. (2017). Water standards vs synergic effects of flouride, heavy metals and hardness in drinking water. Water Science and Technology, 5(1), 55-75.
[26]. Xiaochang, W. (1996). Characteristics of alum coagulation: The influence of suspension concentration on the hydrolysis reaction and adsorption-charge neutralization. Journal of Environmental Chemistry, 15(6), 530-535.
If you have access to this article please login to view the article or kindly login to purchase the article

Purchase Instant Access

Single Article

North Americas,UK,
Middle East,Europe
India Rest of world
USD EUR INR USD-ROW
Online 15 15

Options for accessing this content:
  • If you would like institutional access to this content, please recommend the title to your librarian.
    Library Recommendation Form
  • If you already have i-manager's user account: Login above and proceed to purchase the article.
  • New Users: Please register, then proceed to purchase the article.