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Effect of TiO₂ Modifier Oxide on a B₂O₃ Glass System

P. Naresh*, A. Chitti Babu**, L. Srinivasa Rao***, G. Nagaraju****

* Department of Physics, Velagapudi Ramakrishna Siddhartha Engineering College, Vijayawada, Andhra Pradesh, India.

** Department of Physics, Rajiv Gandhi University of Knowledge and Technologies, (APIIIT), Nazvid, India.

*** Department of Physics, VNR Vignana Jyothi Institute of Engineering and Technology, Hyderabad, Telangana, India.

**** Department of Physics, Acharya Nagarjuna University, Andhra Pradesh, India.

Periodicity:October - December'2019

Abstract

In this paper, Syntherized Zinc-Barium-Borate glasses are doped with various concentration of titanium ion and are characterized by an XRD. The starting material of the glass system is ZnO-BaO-B₂O₃:TiO₂ glasses, which are prepared by conventional melt quenching technique. Densities are measured. Optical absorption spectra and FTIR spectra were recorded at room temperature. Optical absorption studies indicate that the titanium ions do exist in Ti³⁺ and Ti⁴⁺ state. As the content of TiO₂ increases, Ti³⁺ ions acts as modifiers and these may induce NBO’s in the glass network and reduce the samll portion of Ti⁴⁺ ions to Ti³⁺ ions. The IR spectral studies indicate that the structure of these glasses consist of BO₃ and BO₄ groups randomly connected with linkages B-O-B, Zn-O-Zn, B-O-Zn. Finally, the structural changes in the host glass are analyzed with a small variation in the TiO₂concentration. From the results, it can be concluded that the effects of Ti³⁺ions in lead borate glasses is dominated by Ti⁴⁺ ions.

Keywords

Melt-Quenching, Optical Absorption, FT-IR, B₂O₃ Glasses.

How to Cite this Article?

Naresh, P., Babu, A. C., Rao, L. S., and Nagaraju, G. (2019). Effect of TiO₂ Modifier Oxide on a B₂O₃ Glass System. i-manager's Journal on Physical Sciences, 1(1), 1-7.

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