In this paper, Syntherized Zinc-Barium-Borate glasses are doped with various concentration of titanium ion and are characterized by an XRD. The starting material of the glass system is ZnO-BaO-B₂O₃:TiO₂ glasses,  which are prepared by conventional melt quenching technique. Densities are measured. Optical absorption spectra and FTIR spectra were recorded at room temperature. Optical absorption studies indicate that the titanium ions do exist in Ti³⁺ and Ti⁴⁺ state. As the content of TiO₂ increases, Ti³⁺ ions acts as modifiers and these may induce NBO’s in the glass network and reduce the samll portion of Ti⁴⁺ ions to Ti³⁺ ions. The IR spectral studies indicate that the structure of these glasses consist of BO₃ and BO₄ groups randomly connected with linkages B-O-B, Zn-O-Zn, B-O-Zn. Finally, the structural changes in the host glass are analyzed with a small variation in the TiO₂ concentration. From the results, it can be concluded that the effects of Ti³⁺ ions in lead borate glasses is dominated by Ti⁴⁺ ions.