An Advanced Catalytic action for the Hydrogen Evolution Reaction on RGO and ZnO nanoparticle composite

Sunayana Kashyap*, Raj Deep**
*Postgraduate, Department of Biotechnology, D.D.U. Gorakhpur University, Gorakhpur, Uttar Pradesh, India.
**B. Tech Graduate, Department of Mechanical Engineering, Cochin University of Science and Technology, Kochi, Kerala, India.
Periodicity:October - December'2018
DOI : https://doi.org/10.26634/jms.6.3.14861

Abstract

In this work, Zinc Oxide nanoparticle was developed over reduced graphene oxide sheets and cyclic voltammetry was performed with different nanomaterial composites fabricated over electrodes and their graphs were compared. There was an exceptional rise in current, which shows that the composite could be used to catalyse different reactions, which favour transfer of electrons like Hydrogen Reduction Reaction and Oxygen Reduction Reactions. The graphene oxide (GO) was synthesised by improved Hummers method and it was reduced fully by treating it with by L-Ascorbic acid. The composite of Zinc Oxide Nanoparticles and Reduced Graphene Oxide was synthesised and characterised using different characterization techniques.

Keywords

Reduced Graphite Oxide, Indium Tin Oxide, Zinc Oxide Nanoparticles, Cyclic Voltammetry.

How to Cite this Article?

Kashyap, S., and Deep, R. (2018). An Advanced Catalytic Action for the Hydrogen Evolution Reaction on RGO and ZnO Nanoparticle Composite. i-manager’s Journal on Material Science, 6(3), 28-33. https://doi.org/10.26634/jms.6.3.14861

References

[1]. Abdolhosseinzadeh, S., Asgharzadeh, H., & Kim, H. S. (2015). Fast and fully-scalable synthesis of reduced graphene oxide. Scientific Reports, 5, 10160.
[2]. Chen, W., Wang, H., Mao, L., Chen, X., & Shangguan, W. (2014). Influence of loading Pt, RhO2 co-catalysts on photocatalytic overall water splitting over H1.9K0.3La0.5Bi0.1 Ta2O7. Catalysis Communications, 57, 115-118. 
[3]. Chen, X., Chen, S., Lin, C., Jiang, Z., & Shangguan, W. (2015a). Nickels/CdS photocatalyst prepared by flowerlike Ni/Ni (OH)2 precursor for efficiently photocatalytic H2 evolution. International Journal of Hydrogen Energy, 40(2), 998-1004.
[4]. Chen, W., Chu, M., Gao, L., Mao, L., Yuan, J., & Shangguan, W. (2015b). Ni(OH)2 loaded on TaON for enhancing photocatalytic water splitting activity under visible light irradiation. Applied Surface Science, 324, 432-437.
[5]. Jaramillo, T. F., Jørgensen, K. P., Bonde, J., Nielsen, J. H., Horch, S., & Chorkendorff, I. (2007). Identification of active edge sites for electrochemical H2 evolution from MoS2 nanocatalysts. Science, 317(5834), 100-102.
[6]. Levi, M. D., & Aurbach, D. (1997). Simultaneous measurements and modeling of the electrochemical impedance and the cyclic voltammetric characteristics of graphite electrodes doped with lithium. The Journal of Physical Chemistry B, 101(23), 4630-4640.
[7]. Li, D., Müller, M. B., Gilje, S., Kaner, R. B., & Wallace, G. G. (2008). Processable aqueous dispersions of graphene nanosheets. Nature Nanotechnology, 3(2), 101-105.
[8]. Li, Y., Wang, H., Xie, L., Liang, Y., Hong, G., & Dai, H. (2011). MoS nanoparticles grown on graphene: An 2 advanced catalyst for the hydrogen evolution reaction. Journal of the American Chemical Society, 133(19), 7296-7299.
[9]. Lomeda, J. R., Doyle, C. D., Kosynkin, D. V., Hwang, W. F., & Tour, J. M. (2008). Diazonium functionalization of surfactant-wrapped chemically converted graphene sheets. Journal of the American Chemical Society, 130(48), 16201-16206.
[10]. Marcano, D. C., Kosynkin, D. V., Berlin, J. M., Sinitskii, A., Sun, Z., Slesarev, A., ... & Tour, J. M. (2010). Improved synthesis of graphene oxide. ACS Nano, 4(8), 4806-4814.
[11]. Muhich, C. L., Ehrhart, B. D., Al-Shankiti, I., Ward, B. J., Musgrave, C. B., & Weimer, A. W. (2016). A review and perspective of efficient hydrogen generation via solar thermal water splitting. Wiley Interdisciplinary Reviews: Energy and Environment, 5(3), 261-287.
[12]. Shan, C., Yang, H., Han, D., Zhang, Q., Ivaska, A., & Niu, L. (2010). Graphene/AuNPs/chitosan nanocomposites film for glucose biosensing. Biosensors and Bioelectronics, 25(5), 1070-1074.
[13]. Uhl, F. M., & Wilkie, C. A. (2004). Preparation of nanocomposites from styrene and modified graphite oxides. Polymer Degradation and Stability, 84(2), 215- 226.
[14]. Xu, Y., Bai, H., Lu, G., Li, C., & Shi, G. (2008). Flexible graphene films via the filtration of water-soluble noncovalent functionalized graphene sheets. Journal of the American Chemical Society, 130(18), 5856-5857.
[15]. Yu, J., Hai, Y., & Cheng, B. (2011). Enhanced photocatalytic H2 -production activity of TiO2 by Ni (OH)2 cluster modification. The Journal of Physical Chemistry C, 115(11), 4953-4958.
[16]. Zhang, Q., Li, Z., Wang, S., Li, R., Zhang, X., Liang, Z., ... & Li, C. (2016). Effect of redox cocatalysts location on photocatalytic overall water splitting over cubic NaTaO3 semiconductor crystals exposed with equivalent facets. ACS Catalysis, 6(4), 2182-2191.
[17]. Zhu, X., Liu, Q., Zhu, X., Li, C., Xu, M., & Liang, Y. (2012). Reduction of graphene oxide via ascorbic acid and its application for simultaneous detection of dopamine and ascorbic acid. Int. J. Electrochem. Sci., 7, 5172-5184.
If you have access to this article please login to view the article or kindly login to purchase the article

Purchase Instant Access

Single Article

North Americas,UK,
Middle East,Europe
India Rest of world
USD EUR INR USD-ROW
Pdf 35 35 200 20
Online 35 35 200 15
Pdf & Online 35 35 400 25

Options for accessing this content:
  • If you would like institutional access to this content, please recommend the title to your librarian.
    Library Recommendation Form
  • If you already have i-manager's user account: Login above and proceed to purchase the article.
  • New Users: Please register, then proceed to purchase the article.