Box-Behnken Design for the Removal of Manganese From Aqueous Solution By Limonia Acidissima Hull Powder as Adsorbent

D. Krishna*, Santosh Kumar G**
* Associate Professor, Department of Chemical Engineering, M.V.G.R. College of Engineering, Vizianagaram, India.
** Assistant Professor, Department of Chemical Engineering, M.V.G.R. College of Engineering, Vizianagaram, India.
Periodicity:May - July'2015
DOI : https://doi.org/10.26634/jfet.10.4.3473

Abstract

The objective of the present work is to find out the Influence and optimization of parameters like initial Mn (Manganese) concentration (20-100 mg/l), pH (3-5), and biomass dosage (4-6g/l) of Mn (Manganese) biosorption using the design of experiments by Box-Behnken Design (BBD) in response surface methodology. A total of 15 experiments were conducted in the present investigation towards construction of an empirical model. The optimum conditions for maximum removal of Mn (Manganese) from an aqueous solution were as follows: biosorbent dosage (5.25027 g/l), pH (4.05967) and initial Mn (Manganese) concentration (20.0653 mg/l). At the optimized condition, the maximum Mn (Manganese) removal 2 was found to be 90.3692%. The high correlation coefficient (R =0.989) between the model and the experimental data showed that that the model was able to predict the removal of Mn (Manganese) from aqueous solution using Limonia acidissima hull powder efficiently.

Keywords

Biosorption, Mn (Manganese), Box-Behnken Design (BBD), Response Surface Methodology, Limonia Acidissima Hull Powder

How to Cite this Article?

Krishna, D., and Kumar, S. (2015). Box-Behnken Design for the Removal of Manganese From Aqueous Solution By Limonia Acidissima Hull Powder as Adsorbent. i-manager’s Journal on Future Engineering and Technology, 10(4), 8-14. https://doi.org/10.26634/jfet.10.4.3473

References

[1]. Aksu, Z., Ozer, D., Ekiz, H.I., Kutsal, T., Calar.A. (1996). “Investigation of Biosorption of Chromium (VI) on Cladophora Crispata in Two-Staged Batch Reactor”, Environ.Technol., Vol.17, pp. 215-220.
[2]. Alam, M.Z., Muyibi, S.A., Toramae, J. (2007). “statistical optimization of adsorption processes for removal of 2, 4-dichlorophenol by activated carbon derived from oil palm empty fruit bunches”, J.Environ.Sci. Vol.19, pp. 674-677.
[3]. Celik, A., Demirabas, A. (2005). “Removal of heavy metal ions from aqueous solutions via adsorption onto modified lignin wastes”, Energy sources, Vol. 27, pp. 1167- 1177.
[4]. Chakravathi, A.K., Chowadary, S.B., Chakrabarty, S., Chakrabarty, T., Mukherjee, D.C. (1995). “Liquid membrane multiple emulsion process of chromium (VI) separation from waste waters”, Colloids,Surf.A, Vol.103, pp. 59-71.
[5]. Dakiky, M., Kharmics, M., Manassra, A., Mereb, M. (2002). “Selective adsorption of chromium (VI) in industrial waste water using low cost abundantly available adsorbents”, Adv. Environ. Res., Vol. 6, pp. 533-537.
[6]. Huang, S.D., Fann, C.F., Hsiech, H.S. (1982). “Foam separation of chromium (VI) from aqueous solution”, J.Colloid.Interface.Sci., Vol. 89, pp. 504-513.
[7]. John, M.K., Laerhoven, V., Cross, C.H. (1975). “Cadmium, Lead and Zinc accumulate in soils nearer a smother complex”, Environ.Lett., Vol. 10, pp. 25-35.
[8]. Kannan, K. (1995). Fundamentals of Environmental Pollution, S chand Co Limited, New Delhi.
[9]. Kiran, B., Kaushik, A., Kaushik, C.P. (2007). “Response surface methodology approach for optimizing removal of Cr(VI) from aqueous solution using immobilized Cynobacterium”, Chem. Eng. J., Vol. 126, pp.147-153
[10]. Kongsricharoern, N., Polprasert, C. (1996). “Chromium removal by a bipolar electro-chemical precipitation process”, Water.Sci.Technol., Vol. 34, pp.109-116.
[11]. Kortenkamp, A., Casadevali, M., Faux, S.P., Jenner, A., Shayer, O.J., Woodbridge, N., Obrien, P. (1996). “A role for molecular oxygen in the formation of DNA damage during the reduction of the carcinogen chromium (VI) by alutathione”, Arch. Biochem.Biophys., Vol. 329(2), pp.199-208.
[12]. Krishna, D., Padma Sree, R. (2013). “Response surface modeling and optimization of chromium (VI) removal from wastewater using limonia acidissima hull powder”, i-manager’s Journal on Future Engineering and Technology, Vol. 8(2), Nov-Jan 2013, Print ISSN 0973-2632, E-ISSN 2230-7184, pp. 24-32..
[13]. Krishna, D., Suresh, M., Srikhar I.S., Madhuri, N. (2014). “Removal of Manganese from Aqueous Solution By Limonia Acidissima Hull Powder As Adsorbent”. imanager ’s Journal on Future Engineering and Technology, Vol. 9(3), Feb-Apr, 2014, Print ISSN 0973-2632, E-ISSN 2230-7184, pp. 22-30.
[14]. Krishna, D., Padma Sree, R. (2014). “Response surface modeling and optimization of chromium (VI) removal from waste water using custard apple peel powder”, walailak J Sci & Tech, Vol. 11(6), pp. 489-496.
[15]. Krishna, D., Padma Sree, R. (2014). “Response surface modeling and optimization of chromium (VI) removal from waste water using borasus flabellifer coir powder”, Int.J.Appl.Sci.Eng., Vol.11(2), pp.157-167
[16]. Kumar, D.A. (2004). Environmental Chemistry, New age International, New Delhi, 5th Edn., pp.280.
[17]. Low, K.S., Lee, C.K., Ng., A.Y. (1999). “Column study on the sorption of Cr (VI) using quaternized rice hulls”, Bio.reso. Technol., Vol. 68, pp. 205-208.
[18]. Montgomerry D.C. (2001). “Design and Analysis of Experiments”, 5th ed., John Wiley Sons, New York, USA.
[19]. Muthukumar, M., Mohan, D., Rajendran, M. (2003). “Optimization of mix proportions of mineral aggregates using Box- Behnken design of experiments” , Cem.Concr.Res. Vol. 25, pp. 751-758.
[20]. Omgbu, J.A., Iweanya, V.I. (1990). “Dynamic sorption of Pb2+ and Zn2+ with palm kernel husk”, J.Chem.Ed., Vol. 67, pp. 800-801.
[21]. Orthan, Y., Buyukgungor, H. (1993). “The removal of heavy metals by using agricultural wastes, Water” Sci.Technol., Vol. 28, pp. 247-255.
[22]. Pagilla, K.R., Canter, L.W. (1999). “Laboratory studies on remediation of Chromium–contaminated soils”, J.Environ.Eng, Vol.125, pp. 243-248.
[23]. Ross, S.M. (1994). “Toxic metals in soil plant system, John wiley and Sons”, Chichester, pp. 3-26.
[24]. Sawyer, C.N., McCarty, P.L., Parkin, G.F. (2003). “Chemistry for environmental engineering and Science”, Tata McGraw-Hill Publishing, New Delhi, 5th Edn., pp. 660- 661 & 717.
[25]. Seaman, J.C., Bertsch, P.M., Schwallie, L. (1999). “In- Situ Cr (VI) reduction within coarse – textured oxide-coated soil and aquifer systems using Fe (II) solutions”, Environ.Sci.Technol. Vol. 33, pp. 938-944.
[26]. Tiller, K.Y. (1989). “Heavy metals in soil and their environmental significance”, Adv.Soil.Sci., Vol. 9, pp. 113- 142.
[27]. Tiravanti, G., Petruzzelli, D., Passino, R. (1997). “Pretreatment of tannery waste waters by an ionexchange process for Cr (III) removal and recovery”, Water.Sci.Technol. Vol. 36, pp. 197-207.
[28]. Toles, C.A., Marshell, W.E., Johns, M.M. (1997). “GAC from nutshells for the uptake of metal ions and organic compounds”, Carbon, Vol. 35, pp. 1414-1470.
[29]. Vazquez, G., Gonzalaez-Alvarez, J., Freire, S., Lopez-Lorenzo, M., Antorrena, G. (2002). “Removal of cadmium and mercury ions from aqueous solution by sorption on treated pinus pinaster bark: kinetics and isotherms”, Bio.reso. Technol., Vol. 82, pp. 247-251.
[30]. Veglio, F., Beolchini, F. (1997). “Removal of metals by biosorption: a review”, Hydrometallurgy, Vol. 44, pp. 301- 316.
[31]. Volesky, B., Holan, Z.R. (1995). Biosorption of heavy metals, Biotechnology. Prog. 11, 235-250.
[32]. Zhou, X., Korenaga, T., Takahashi, T Moriwake, T Shinoda, S. (1993). “A process monitoring/controlling system for the treatment of waste water containing (VI)”, Water Res, Vol. 27, pp. 1049-1059.
If you have access to this article please login to view the article or kindly login to purchase the article

Purchase Instant Access

Single Article

North Americas,UK,
Middle East,Europe
India Rest of world
USD EUR INR USD-ROW
Pdf 35 35 200 20
Online 35 35 200 15
Pdf & Online 35 35 400 25

Options for accessing this content:
  • If you would like institutional access to this content, please recommend the title to your librarian.
    Library Recommendation Form
  • If you already have i-manager's user account: Login above and proceed to purchase the article.
  • New Users: Please register, then proceed to purchase the article.