This paper presents an experimental investigation on the effect of partial replacement of cement by metakalion by various percentages viz 0%, 10%, 20%, and 30% on the properties of high performance concrete, when it is subjected to acid attack. An aggregate binder ratio of 2 and different water binder ratios viz 0.3, 0.35, 0.40 and 0.45 was used in this investigation. Concrete specimens of size 150 x 150 x 150 mm were casted to find residual compressive strength and specimens of size 100 x 100 x 100mm were casted to find percentage weight loss; both the sizes of specimens were casted and cured as per IS specification. After 28 days water curing, the concrete specimens were kept immersed in 5% concentrated acid solution for 30, 60 and 90 days for observation. Before immersion, they were weighed accurately and after required days of immersion and observation, the specimens were removed from acid media, weighed accurately and tested for their compressive strength; weight loss and hardness of concrete were studied. The various results which indicate the effect of replacement of cement by metakalion on HPC are presented in this paper to draw useful conclusions. The results were compared with reference mix. Test results indicate that use of replacement cement by metakalion in HPC has improved performance of concrete up to 10%.