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Structural and Luminescent Property of Europium Oxide Doped Boro Tellurite Glasses

Devaraja C *, Jagadeesha Gowda G V**, Eraiah B***, Keshavamurthy K****

*-**,**** Department of Physics, Sapthagiri College of Engineering, Bangalore, Karnataka, India..

*** Department of Physics, Bengaluru University, Bangalore, Karnataka, India.

Periodicity:April - June'2020
DOI : https://doi.org/10.26634/jms.8.1.16060

Abstract

Europium oxide doped boro tellurite glasses of different compositions have been synthesized by using melt quenching procedure. The synthesized glasses contain a composition of (70-x) B₂O₃-15TeO₂ -10Na₂O-5PbO-xEu₂O₃ with x = 0, 0.1, 0.3, and 0.4 mol%. Raman spectroscopic investigations on prepared glasses have been carried out to study the structures and vibrations of atoms in the glass network. By Raman spectra, it is clear that the prepared glass samples are possessing the boroxol rings and also found the different vibrations in Te-O-Te bonds. The emission spectra were done by spectrofluorometer techniques to investigate the luminescent properties of these glasses with excitation wavelength as 394 nm and emission wavelength as 612 nm.

Keywords

Boro-Tellurite Glasses, Rare Earth Ions, Raman Spectroscopy, Photoluminescence.

How to Cite this Article?

Devaraja, C., Gowda, G. V. J., Eraiah, B., and Keshavamurthy, K. (2020). Structural and Luminescent Property of Europium Oxide Doped Boro Tellurite Glasses. i-manager's Journal on Material Science, 8(1), 39-44. https://doi.org/10.26634/jms.8.1.16060

References

[1]. Eraiah, B., Smitha, M. G., & Anavekar, R. V. (2010). Elastic properties of lead-phosphate glasses doped with samarium trioxide. Journal of Physics and Chemistry of Solids, 71(3), 153-155. https://doi.org/10.1016/j.jpcs.2009. 10.009

[2]. Giridhar, P., Bhushana Reddy, M., Neelima, G., Ramanaiah, R., Nagamuni Reddy, K., Sahadeva Reddy, V., & Sudhakar Reddy, B. (2016). Optical analysis of RE3+ (RE= Pr3+ , Er3+ and Nd3+ ): cadmium lead boro tellurite glasses. Luminescence, 31(6), 1237-1241. https://doi.org/ 10.1002/bio.3096

[3]. Gowda, G. J., Eraiah, B., & Anavekar, R. V. (2015). Ionic conductivity of praseodymium doped silver-borate glasses. Journal of Alloys and Compounds, 620, 192-196. https://doi.org/10.1016/j.jallcom.2014.09.019

[4]. Gowda, V. V., & Anavekar, R. V. (2007). Electrical conductivity studies of AgI–Ag2 O–B2 O3 –TeO2 glasses. Journal of Materials Science, 42(11), 3816-3824. https:// doi.org/10.1007/s10853-006-0408-x

[5]. Herrmann, A., Kuhn, S., Tiegel, M., & Rüssel, C. (2014). Fluorescence properties of Eu3+- doped alumino silicate glasses. Optical Materials, 37, 293-297. https://doi.org/10. 1016/j.optmat.2014.06.011

[6]. Jiménez, J. A. (2015). Photoluminescence of Eu3+- doped glasses with Cu2+ impurities. Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy, 145, 482-486. https://doi.org/10.1016/j.saa.2015.03.047

[7]. Kalpana, T., Brik, M. G., Sudarsan, V., Naresh, P., Kumar, V. R., Kityk, I. V., & Veeraiah, N. (2015). Influence of Al3+ ions on luminescence efficiency of Eu3+ ions in barium borophosphate glasses. Journal of Non-Crystalline Solids, 419, 75-81. https://doi.org/10.1016/j.jnoncrysol.2015.03.033

[8]. Kaur, R., Khanna, A., González-Barriuso, M., González, F., & Chen, B. (2018). Structural, optical and thermal properties of glass and anti-glass phases in strontium tellurite and borotellurite systems doped with europium. Materials Research Bulletin, 106, 288-295. https://doi.org/ 10.1016/j.materresbull.2018.06.020

[9]. Kostova, I., Patronov, G., & Tonchev, D. (2018). Luminescent Properties of Rare Earth Doped Zno-b2o3 –p2o5 Glasses. Journal of Chemical Technology and Metallurgy, 53(6), 1087-1094.

[10]. Kumar, V., Pandey, A., Ntwaeaborwa, O. M., Dutta, V., & Swart, H. C. (2017). Structural and luminescence properties of Eu3+/Dy3+ embedded sodium silicate glass for multicolour emission. Journal of Alloys and Compounds, 708, 922-931. https://doi.org/10.1016/j.jallcom.2017.03. 061

[11]. Maheshvaran, K., & Marimuthu, K. (2012). Concentration dependent Eu3+ doped boro-tellurite glasses—Structural and optical investigations. Journal of luminescence, 132(9), 2259-2267. https://doi.org/10. 1016/j.jlumin.2012.04.022

[12]. Maheshvaran, K., Uma, V., & Marimuthu, K. (2013). Spectroscopic studies on Er3+ doped boro-tellurite glasses. Transactions of the Indian Ceramic Society, 72(1), 21-23. https://doi.org/10.1080/0371750X.2013.793990

[13]. Mahraz, Z. A. S., Sahar, M. R., & Ghoshal, S. K. (2014). Influence of Er3+ dopants on optical properties of borotellurite glass. In Advanced Materials Research (Vol. 895, pp. 211-215). Trans Tech Publications Ltd. https://doi.org/10. 4028/www.scientific.net/AMR.895.211

[14]. Murugan, G. S., Suzuki, T., & Ohishi, Y. (2006). Raman characteristics and nonlinear optical properties of tellurite and phosphotellurite glasses containing heavy metal oxides with ultrabroad Raman bands. Journal of Applied Physics, 100(2), 1-6. https://doi.org/10.1063/1.2215218

[15]. Nico, C., Fernandes, R., Graça, M. P. F., Elisa, M., Sava, B. A., Monteiro, R. C. C., & Monteiro, T. (2014). Eu3+ luminescence in alumino phosphate glasses. Journal of Luminescence, 145, 582-587. https://doi.org/10.1016/j.jlumin.2013.08.041

[16]. Rada, S., Culea, M., & Culea, E. (2008). Structure of TeO2 B2 O3 glasses inferred from infrared spectroscopy and DFT calculations. Journal of Non-Crystalline Solids, 354(52- 54), 5491-5495. https://doi.org/10.1016/j.jnoncrysol.2008. 09.009

[17]. Sayyed, M. I. (2016). Bismuth modified shielding properties of zinc boro-tellurite glasses. Journal of Alloys and Compounds, 688, 111-117. https://doi.org/10.1016/j. jallcom.2016.07.153

[18]. Shigihalli, N. B., Rajaramakrishna, R., & Anavekar, R. V. (2011, July). Optical properties of Eu3+ doped lead borate tellurite and zinc borate tellurite glasses. In AIP Conference Proceedings, 1349(1), 547-548. American Institute of Physics. https://doi.org/10.1063/1.3605975

[19]. Sun, X. Y., Zhang, X., Chen, H. H., Hu, Q. L., Wang, W. F., Zhang, Z. J., & Zhao, J. T. (2014). Investigation on the luminescent properties of Eu3+ activated dense oxyfluoride borogermanate scintillating glasses. Journal of Noncrystalline Solids, 404, 162-166. https://doi.org/10.1016/j. jnoncrysol.2014.08.020

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